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Brad Pitt's seriously awkward interview with Zach Galifianakis

Brad Pitt was put on the spot by Zach Galifanakis in his latest episode of Between Two Ferns. Photos: Getty Images

Brad Pitt was the latest star to be interviewed on Zach Galifianakis' hilarious web series for Funny or Die, Between Two Ferns in which he grills famous people about their personal lives.

The 52-year-old was there to promote her new WW2 film Fury - or furry as the host referred to it - however it took a turn for the worse when the topic of Brad's ex wife, Jennifer Aniston came up.

Brad appeared extremely uncomfortable when The Hangover star asked if Brad and his wife, Angelina Jolie, have chemistry similar to a famous love story like Ross and Rachel, who was of course Jennifer's character on Friends.

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"Tell me, when you first laid eyes on Angelina, is it like one of those classical love stories, like when Ross first saw Rachel? You know that show Friends, have you seen it?" he asked.

Brad, who famously guest-starred in an episode of the popular sitcom, looked noticeably uncomfortable as he refused to answer the question.

Things got even more uncomfortable when Zach then blasted the show's popular theme song, I'll Be There for You.

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Brad simply said, "I like that song."

The awkwardness didn't end there though, Zach also poked fun at 39-year-old Angelina, saying: "Is it hard for you to maintain a sun tan because you live in your wife's shadow? Because, I too, I had a romantic fling that was public and it got on my nerves because she kind of outshines me. I had the same thing with [Condoleezza Rice]."

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